Synthesis and structures of a pentanuclear Al(III) phosphonate cage, an In(III) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3.
Identifieur interne : 000A16 ( Main/Exploration ); précédent : 000A15; suivant : 000A17Synthesis and structures of a pentanuclear Al(III) phosphonate cage, an In(III) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3.
Auteurs : RBID : pubmed:22886111Abstract
A cationic, pentanuclear aluminium phosphonate cage, [L(4)Al(5)Cl(6)(THF)(6)]Cl, 1, supported by (phthalimidomethyl) phosphonate, (L), has been synthesized and characterized. This polynuclear cage features the phosphonate ligand in an unusual coordination mode, supporting five aluminium atoms in two different environments. In comparison, the aqueous reaction of LH(2) with In(ClO(4))(3) afforded [{(LH)In(H(2)O)}(H(2)O)(2)(ClO(4))](n), 2, an indium(III) phosphonate coordination polymer, that has been crystallographically characterized. Reactions of the corresponding phosphonate ester, diethyl (phthalimidomethyl) phosphonate, (L'), with GaI(3) and InCl(3) afforded the simple coordination complexes, [L'·GaI(3)], 3, and [L'·InCl(3)(THF)], 4.
DOI: 10.1039/c2dt31280h
PubMed: 22886111
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthesis and structures of a pentanuclear Al(III) phosphonate cage, an In(III) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3.</title><author><name sortKey="Richards, Anne F" uniqKey="Richards A">Anne F Richards</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, La Trobe Institute for Molecular Sciences, Kingsbury Drive, Melbourne, Australia. a.richards@latrobe.edu.au</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Department of Chemistry, La Trobe Institute for Molecular Sciences, Kingsbury Drive, Melbourne</wicri:regionArea></affiliation></author><author><name sortKey="Beavers, Christine M" uniqKey="Beavers C">Christine M Beavers</name></author></titleStmt><publicationStmt><date when="2012">2012</date><idno type="doi">10.1039/c2dt31280h</idno><idno type="RBID">pubmed:22886111</idno><idno type="pmid">22886111</idno><idno type="wicri:Area/Main/Corpus">000B28</idno><idno type="wicri:Area/Main/Curation">000B28</idno><idno type="wicri:Area/Main/Exploration">000A16</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A cationic, pentanuclear aluminium phosphonate cage, [L(4)Al(5)Cl(6)(THF)(6)]Cl, 1, supported by (phthalimidomethyl) phosphonate, (L), has been synthesized and characterized. This polynuclear cage features the phosphonate ligand in an unusual coordination mode, supporting five aluminium atoms in two different environments. In comparison, the aqueous reaction of LH(2) with In(ClO(4))(3) afforded [{(LH)In(H(2)O)}(H(2)O)(2)(ClO(4))](n), 2, an indium(III) phosphonate coordination polymer, that has been crystallographically characterized. Reactions of the corresponding phosphonate ester, diethyl (phthalimidomethyl) phosphonate, (L'), with GaI(3) and InCl(3) afforded the simple coordination complexes, [L'·GaI(3)], 3, and [L'·InCl(3)(THF)], 4.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">22886111</PMID><DateCreated><Year>2012</Year><Month>09</Month><Day>06</Day></DateCreated><DateCompleted><Year>2013</Year><Month>01</Month><Day>08</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1477-9234</ISSN><JournalIssue CitedMedium="Internet"><Volume>41</Volume><Issue>37</Issue><PubDate><Year>2012</Year><Month>Oct</Month><Day>7</Day></PubDate></JournalIssue><Title>Dalton transactions (Cambridge, England : 2003)</Title><ISOAbbreviation>Dalton Trans</ISOAbbreviation></Journal><ArticleTitle>Synthesis and structures of a pentanuclear Al(III) phosphonate cage, an In(III) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3.</ArticleTitle><Pagination><MedlinePgn>11305-10</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c2dt31280h</ELocationID><Abstract><AbstractText>A cationic, pentanuclear aluminium phosphonate cage, [L(4)Al(5)Cl(6)(THF)(6)]Cl, 1, supported by (phthalimidomethyl) phosphonate, (L), has been synthesized and characterized. This polynuclear cage features the phosphonate ligand in an unusual coordination mode, supporting five aluminium atoms in two different environments. In comparison, the aqueous reaction of LH(2) with In(ClO(4))(3) afforded [{(LH)In(H(2)O)}(H(2)O)(2)(ClO(4))](n), 2, an indium(III) phosphonate coordination polymer, that has been crystallographically characterized. Reactions of the corresponding phosphonate ester, diethyl (phthalimidomethyl) phosphonate, (L'), with GaI(3) and InCl(3) afforded the simple coordination complexes, [L'·GaI(3)], 3, and [L'·InCl(3)(THF)], 4.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Richards</LastName><ForeName>Anne F</ForeName><Initials>AF</Initials><Affiliation>Department of Chemistry, La Trobe Institute for Molecular Sciences, Kingsbury Drive, Melbourne, Australia. a.richards@latrobe.edu.au</Affiliation></Author><Author ValidYN="Y"><LastName>Beavers</LastName><ForeName>Christine M</ForeName><Initials>CM</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>08</Month><Day>13</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Dalton Trans</MedlineTA><NlmUniqueID>101176026</NlmUniqueID><ISSNLinking>1477-9226</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2012</Year><Month>8</Month><Day>13</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2012</Year><Month>9</Month><Day>5</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>8</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>8</Month><Day>14</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>8</Month><Day>14</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1039/c2dt31280h</ArticleId><ArticleId IdType="pubmed">22886111</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000A16 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000A16 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:22886111
|texte= Synthesis and structures of a pentanuclear Al(III) phosphonate cage, an In(III) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:22886111" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a IndiumV2
| This area was generated with Dilib version V0.5.76. |  |